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1

(β-Amino alcohol)(arene)ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Functionalized Ketones − Scope, Isolation of the Catalytic Intermediates, and Deactivation Processes

Kathelyne Everaere, André Mortreux, Michel Bulliard, Johannes Brussee, Arne van der Gen, Guy Nowogrocki, Jean-François Carpentier

Journal:

European Journal of Organic Chemistry

Année:

2001

Langue:

english

Fichier:

PDF, 627 KB

english, 2001

2

Formation of Enantiomerically Pure 1-Fluorovinyl and 1-Fluoromethyl Sulfoxides

Jan Hein van Steenis, Philip W. S. Boer, Harald A. van der Hoeven, Arne van der Gen

Journal:

European Journal of Organic Chemistry

Année:

2001

Langue:

english

Fichier:

PDF, 345 KB

english, 2001

3

Development of a process model to describe the synthesis of (R)-mandelonitrile by Prunus amygdalus hydroxynitrile lyase in an aqueous–organic biphasic reactor

Wouter F. Willeman, Pieter Jan Gerrits, Ulf Hanefeld, Johannes Brussee, Adrie J. J. Straathof, Arne van der Gen, Joseph J. Heijnen

Journal:

Biotechnology and Bioengineering

Année:

2002

Langue:

english

Fichier:

PDF, 158 KB

english, 2002

4

Synthesis of chiral diaza-18-crown-6 derivatives from optically active diethanolamines

de Vries, Erik F. J., Steenwinkel, Pablo, Brussee, Johannes, Kruse, Chris G., van der Gen, Arne

Journal:

Journal of Organic Chemistry

Année:

1993

Langue:

english

Fichier:

PDF, 1.46 MB

english, 1993

5

Synthesis of terminal monofluoro olefins

van Steenis, Jan Hein, der Gen, Arne van

Journal:

Journal of the Chemical Society Perkin Transactions 1

Année:

2002

Langue:

english

Fichier:

PDF, 500 KB

english, 2002

6

Intramolecular Cycloaddition Reactions of ω-Unsaturated Chiral Nitrones

Jan Marcus, Johannes Brussee, Arne van der Gen

Journal:

European Journal of Organic Chemistry

Année:

1998

Langue:

english

Fichier:

PDF, 151 KB

english, 1998

7

Stereoselective Synthesis of (E)-Vinyl Sulfoxides by the Horner−Wittig Reaction

Jan Hein van Steenis, Joseph Johannes Gerardus Steven van Es, Arne van der Gen

Journal:

European Journal of Organic Chemistry

Année:

2000

Langue:

english

Fichier:

PDF, 299 KB

english, 2000

8

Stereoselective Synthesis of (2R,5R)- and (2S,5R)-5-Hydroxylysine

Adrianus M. C. H. van den Nieuwendijk, Nicole M. A. J. Kriek, Johannes Brussee, Jacques H. van Boom, Arne van der Gen

Journal:

European Journal of Organic Chemistry

Année:

2000

Langue:

english

Fichier:

PDF, 374 KB

english, 2000

9

Synthesis and Horner−Wittig Chemistry of (Fluoromethyl)diphenylphosphane Oxide

Jan Hein van Steenis, Arne van der Gen

Journal:

European Journal of Organic Chemistry

Année:

2001

Langue:

english

Fichier:

PDF, 466 KB

english, 2001

10

A Structural Study of Selenobenzamides: Crystal Structures and Dynamic 13C NMR

Pieter A. Otten, Syb Gorter, Arne Van Der Gen

Journal:

European Journal of Inorganic Chemistry

Année:

1997

Langue:

english

Fichier:

PDF, 620 KB

english, 1997

11

ChemInform Abstract: Synthesis of Reduced Collagen Crosslinks.

Adrianus M. C. H. van den Nieuwendijk, Jorg C. J. Benningshof, Volker Wegmann, Ruud A. Bank, Johan M. te Koppele, Johannes Brussee, Arne van der Gen

Journal:

Année:

1999

Fichier:

PDF, 29 KB

1999

12

ChemInform Abstract: Diastereoselective Addition of HCN to Garner′s Aldehyde.

Jan Marcus, Guido W. M. Vandermeulen, Johannes Brussee, Arne van der Gen

Journal:

Année:

1999

Fichier:

PDF, 27 KB

1999

13

ChemInform Abstract: Synthesis of γ-Hydroxy-α,β-unsaturated Esters and Nitriles from Chiral Cyanohydrins.

Jan Marcus, Pauline J. van Meurs, Adrianus M. C. H. van den Nieuwendijk, Mathieu Porchet, Johannes Brussee, Arne van der Gen

Journal:

Année:

2000

Fichier:

PDF, 32 KB

2000

14

ChemInform Abstract: Stereoselective Synthesis of (E)-Vinyl Sulfoxides by the Horner—Wittig Reaction.

Jan Hein van Steenis, Joseph Johannes Gerardus Steven van Es, Arne van der Gen

Journal:

Année:

2001

Fichier:

PDF, 30 KB

2001

15

ChemInform Abstract: Biocatalysis in the Enantioselective Formation of Chiral Cyanohydrins, Valuable Building Blocks in Organic Synthesis

Johannes Brussee, Arne van der Gen

Journal:

Année:

2001

Fichier:

PDF, 24 KB

2001

16

ChemInform Abstract: Difficult Substrates in the R-Hydroxynitrile Lyase Catalyzed Hydrocyanation Reaction: Application of the Mass Transfer Limitation Principle in a Two-Phase System.

Pieter Jan Gerrits, Jan Marcus, Lemonia Birikaki, Arne van der Gen

Journal:

Année:

2001

Fichier:

PDF, 30 KB

2001

17

ChemInform Abstract: Chemoenzymatic Synthesis of Fmoc-Protected (2S,3S)-2-Hydroxy-3-amino Acids and Their Application in the Synthesis of an α-Hydroxylated β-Hexapeptide.

Reynier A. Tromp, Michael van der Hoeven, Alessia Amore, Johannes Brussee, Mark Overhand, Gijs A. van der Marel, Arne van der Gen

Journal:

Année:

2001

Fichier:

PDF, 32 KB

2001

18

ChemInform Abstract: Stereoselective Biocatalytic Formation of Cyanohydrins, Versatile Building Blocks for Organic Synthesis

Arne Van Der Gen, Johannes Brussee

Journal:

Année:

2001

Fichier:

PDF, 24 KB

2001

19

ChemInform Abstract: (β-Amino alcohol)(arene)ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Functionalized Ketones — Scope, Isolation of the Catalytic Intermediates, and Deactivation Processes.

Kathelyne Everaere, Andre Mortreux, Michel Bulliard, Johannes Brussee, Arne van der Gen, Guy Nowogrocki, Jean-Francois Carpentier

Journal:

Année:

2002

Langue:

english

Fichier:

PDF, 42 KB

english, 2002

20

ChemInform Abstract: Formation of Enantiomerically Pure 1-Fluorovinyl and 1-Fluoromethyl Sulfoxides.

Jan Hein van Steenis, Philip W. S. Boer, Harald A. van der Hoeven, Arne van der Gen

Journal:

Année:

2002

Langue:

english

Fichier:

PDF, 35 KB

english, 2002

21

ChemInform Abstract: Synthesis and Horner—Wittig Chemistry of (Fluoromethyl)diphenylphosphane Oxide.

Jan Hein van Steenis, Arne van der Gen

Journal:

Année:

2002

Langue:

english

Fichier:

PDF, 41 KB

english, 2002

22

Synthesis of Terminal Monofluoro Olefins.

Jan Hein van Steenis, Arne van der Gen

Journal:

Année:

2003

Fichier:

PDF, 48 KB

2003

23

Synthesis of Fmoc-Protected (2S,3S)-2-Hydroxy-3-amino Acids from a Furyl Substituted Chiral Cyanohydrin.

Reynier A. Tromp, Michael van der Hoeven, Alessia Amore, Johannes Brussee, Mark Overhand, Gijs A. van der Marel, Arne van der Gen

Journal:

Année:

2003

Fichier:

PDF, 161 KB

2003

24

Stereochemistry of Intramolecular Diels—Alder Furan (IMDAF) Reactions of Furyl-Substituted Chiral Ethanolamides.

Reynier A. Tromp, Johannes Brussee, Arne van der Gen

Journal:

Année:

2004

Fichier:

PDF, 146 KB

2004

25

Conversion of Chiral Unsaturated Cyanohydrins into Chiral Carba- and Heterocycles via Ring-Closing Metathesis.

Adrianus M. C. H. van den Nieuwendijk, Amar B. T. Ghisaidoobe, Herman S. Overkleeft, Johannes Brussee, Arne van der Gen

Journal:

Année:

2005

Fichier:

PDF, 35 KB

2005

26

Synthesis of (R)- and (S)-5-(Hydroxymethyl)-3-isopropyloxazolidin-2-one, intermediates in the preparation of optically active β-blockers

Erwin G. J. C. Warmerdam, Johannes Brussee, Arne van der Gen, Chris G. Kruse

Journal:

Helvetica Chimica Acta

Année:

1994

Langue:

english

Fichier:

PDF, 332 KB

english, 1994

27

A Horner-Wittig approach to S,N-ketene acetals: Acid-catalyzed hydrolysis of S,N-ketene acetals to (S)-thioesters

Pieter A. Otten, Njord Oskam, Arne van der Gen

Journal:

Année:

1996

Langue:

english

Fichier:

PDF, 484 KB

english, 1996

28

A Horner-Wittig synthesis of 1-chlorovinyl sulfoxides

Pieter A. Otten, Honorine M. Davies, Arne van der Gen

Journal:

Tetrahedron Letters

Année:

1995

Langue:

english

Fichier:

PDF, 174 KB

english, 1995

29

Asymmetric epoxidation of chiral allylic alcohols

Erwin G.J.C. Warmerdam, Adrianus M.C.H. van den Nieuwendijk, Johannes Brussee, Chris G. Kruse, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1996

Langue:

english

Fichier:

PDF, 654 KB

english, 1996

30

Conversion of chiral unsaturated cyanohydrins into chiral carba- and heterocycles via ring-closing metathesis

Adrianus M.C.H. van den Nieuwendijk, Amar B.T. Ghisaidoobe, Herman S. Overkleeft, Johannes Brussee, Arne van der Gen

Journal:

Année:

2004

Langue:

english

Fichier:

PDF, 269 KB

english, 2004

31

Synthesis of γ-Hydroxy-α,β-unsaturated Esters and Nitriles from Chiral Cyanohydrins

Jan Marcus, Pauline J. van Meurs, Adrianus M.C.H. van den Nieuwendijk, Mathieu Porchet, Johannes Brussee, Arne van der Gen

Journal:

Année:

2000

Langue:

english

Fichier:

PDF, 145 KB

english, 2000

32

Inversion of the configuration of cyanohydrins by a mitsunobu esterification reaction

Erwin G.J.C. Warmerdam, Johannes Brussee, Chris G. Kruse, Arne van der Gen

Journal:

Année:

1993

Langue:

english

Fichier:

PDF, 569 KB

english, 1993

33

A one-pot reduction-transimition-reduction synthesis of N-substituted β-ethanolamines from cyanohydrins

Peter Zandbergen, Adrianus M.C.H. van den Niewendijk, Johannes Brussee, Arne van der Gen, Chris G. Kruse

Journal:

Année:

1992

Langue:

english

Fichier:

PDF, 422 KB

english, 1992

34

Acid-catalyzed solvolysis of polyenol ethers. III. Effect of the alkoxy moiety

Saskia A.M. Nieuwenhuis, Louis B.J. Vertegaal, Marian C. de Zoete, Arne van der Gen

Journal:

Année:

1994

Langue:

english

Fichier:

PDF, 1.92 MB

english, 1994

35

Remarkable electrophilic properties of the pentaenol ether system of fecapentaene-12.

Paul P de Wit, Hart van der Steeg, Arne van der Gen

Journal:

Tetrahedron Letters

Année:

1986

Langue:

english

Fichier:

PDF, 238 KB

english, 1986

36

Novel applications of α-aminosubstituted diphenylphosphine oxides. The conversion of aldehydes into α-aminomethylketones.

Nico L.J.M. Broekhof, Arne van der Gen

Journal:

Tetrahedron Letters

Année:

1981

Langue:

english

Fichier:

PDF, 200 KB

english, 1981

37

Stereoselective synthesis of β-hydroxy-α-amino acids from chiral cyanohydrins.

Peter Zandbergen, Johannes Brussee, Arne van der Gen, Chris G. Kruse

Journal:

Tetrahedron: Asymmetry

Année:

1992

Langue:

english

Fichier:

PDF, 317 KB

english, 1992

38

Chiral diethanolamines and their lithium alcoholates as catalysts in the enantioselective alkylation of benzaldehyde by diethylzinc.

Erik F.J. de Vries, Johannes Brussee, Chris G. Knise, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1993

Langue:

english

Fichier:

PDF, 306 KB

english, 1993

39

Magnesium ion mediated stereospecific formation of N-substituted ethanolamines during reductive amination

Johannes Brussee, Rolf A.T.M. van Benthem, C.G. Kruse, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1990

Langue:

english

Fichier:

PDF, 269 KB

english, 1990

40

Stereoselective reduction of prochiral ketones, using aluminum hydride reagents prepared from lialh4 and chiral diethanolamines.

Erik F.J. de Vries, Johannes Brussee, Chris G. Knise, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1994

Langue:

english

Fichier:

PDF, 593 KB

english, 1994

41

Chemoenzymatic synthesis of Fmoc-protected (2S,3S)-2-hydroxy-3-amino acids and their application in the synthesis of an α-hydroxylated β-hexapeptide

Reynier A. Tromp, Michael van der Hoeven, Alessia Amore, Johannes Brussee, Mark Overhand, Gijs A. van der Marel, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

2001

Langue:

english

Fichier:

PDF, 91 KB

english, 2001

42

Difficult substrates in the R-hydroxynitrile lyase catalyzed hydrocyanation reaction: application of the mass transfer limitation principle in a two-phase system

Pieter J. Gerrits, Jan Marcus, Lemonia Birikaki, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

2001

Langue:

english

Fichier:

PDF, 104 KB

english, 2001

43

Synthesis of Fmoc-protected (2S,3S)-2-hydroxy-3-amino acids from a furyl substituted chiral cyanohydrin

Reynier A. Tromp, Michael van der Hoeven, Alessia Amore, Johannes Brussee, Mark Overhand, Gijs A. van der Marel, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

2003

Langue:

english

Fichier:

PDF, 210 KB

english, 2003

44

Direct conversion of chiral cyanohydrins to chiral nitrones by transimination

Edith Hulsbos, Jan Marcus, Johannes Brussee, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1997

Langue:

english

Fichier:

PDF, 436 KB

english, 1997

45

Diastereoselective addition of HCN to Garner's aldehyde

Jan Marcus, Guido W.M Vandermeulen, Johannes Brussee, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1999

Langue:

english

Fichier:

PDF, 115 KB

english, 1999

46

Synthesis of reduced collagen crosslinks

Adrianus M.C.H van den Nieuwendijk, Jorg C.J Benningshof, Volker Wegmann, Ruud A Bank, Johan M te Koppele, Johannes Brussee, Arne van der Gen

Journal:

Bioorganic & Medicinal Chemistry Letters

Année:

1999

Langue:

english

Fichier:

PDF, 215 KB

english, 1999

47

The use of sulfenyl halides in the synthesis of mercapturic acids and their esters

Wim Buijs, Arne van der Gen, Mohammed I. A. Eid, Willem Onkenhout, Nico P. E. Vermeulen

Journal:

Recueil des Travaux Chimiques des Pays-Bas

Année:

1986

Langue:

english

Fichier:

PDF, 538 KB

english, 1986

48

The use of a double Wolff-Kishner reduction in the preparation of aceanthrene and aceanthrylene

Jos C. Olde Boerrigter, Patrick P. J. Mulder, Arne van der Gen, Jan Cornelisse, Johan Lugtenburg, Georges R. Mohn

Journal:

Recueil des Travaux Chimiques des Pays-Bas

Année:

1989

Langue:

english

Fichier:

PDF, 129 KB

english, 1989

49

Synthesis of indoles using (N-arylaminomethyl)diphenylphosphine oxides

Jan Zorgdrager, Nico L. J. M. Broekhof, Arne van der Gen

Journal:

Recueil des Travaux Chimiques des Pays-Bas

Année:

1989

Langue:

english

Fichier:

PDF, 431 KB

english, 1989

50

An enantioselective synthesis of the Williams glycine template

Adrianus M.C.H. van den Nieuwendijk, Erwin G.J.C. Warmerdam, Johannes Brussee, Arne van der Gen

Journal:

Tetrahedron: Asymmetry

Année:

1995

Langue:

english

Fichier:

PDF, 343 KB

english, 1995